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Nano-sized transition-metal oxides as negative …

Here we report that electrodes made of nanoparticles of transition-metal oxides (MO, where M is Co, Ni, Cu or Fe) demonstrate …

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High performance silicon electrode enabled by titanicone coating …

Silicon is a promising material as a negative electrode for LIBs. It can store almost 4 mol of Li per mol of Si ... Park, M. H. et al. Silicon nanotube battery anodes. Nano Lett. 9, 3844–3847 ...

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Electrochemical Preparation of Nano-Sized Silicon as a Lithium …

Highly pure silicon is an important component in photovoltaic applications and has potential in battery technology. In this study, the electrochemical behavior of Si …

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Mechanochemical synthesis of Si/Cu3Si-based composite as negative electrode materials for lithium ion battery …

Mechanochemical synthesis of Si/Cu3Si-based composite as negative electrode materials for lithium ion battery ... CuO and Si upon HEMM resulting in formations of copper silicide and silicon oxide ...

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Mechanisms and Product Options of Magnesiothermic Reduction of Silica to Silicon for Lithium-Ion Battery …

Mesoporous silicon microspheres fabricated via in situ magnesiothermic reduction of silicon oxide as a high-performance anode material for lithium–ion batteries. J. Solid State Electrochem. 19, 935–939. doi: 10.1007/s10008-014-2693-7

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Improved electrochemical performance of boron-doped SiO negative electrode materials in lithium-ion batteries …

negative electrode materials in Li-ion batteries. Transmission electron microscope (TEM) results reveal that thermally treated SiO at 900 C (H–SiO) consists of uniformly dispersed nano-crystalline Si (nc-Si) in an amorphous silicon oxide (SiO x ...

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Phosphorus-doped silicon nanoparticles as high performance LIB negative electrode | Journal of Materials …

Silicon is getting much attention as the promising next-generation negative electrode materials for lithium-ion batteries with the advantages of abundance, high theoretical specific capacity and environmentally friendliness. In this work, a series of phosphorus (P)-doped silicon negative electrode materials (P-Si-34, P-Si-60 and P-Si …

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Comparison of commercial silicon-based anode materials for the design of a high-energy lithium-ion battery | Nano …

Silicon (Si) is considered a potential alternative anode for next-generation Li-ion batteries owing to its high theoretical capacity and abundance. However, the commercial use of Si anodes is hindered by their large volume expansion (∼ 300%). Numerous efforts have been made to address this issue. Among these efforts, Si-graphite …

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Electrolyte design for lithium-ion batteries with a cobalt-free …

The chemistry of LIBs, with carbon-based negative electrodes (anodes) and metal oxide-based positive electrodes (cathodes), has remained largely unchanged …

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Enhanced Performance of Silicon Negative Electrodes …

Silicon is considered as one of the most promising candidates for the next generation negative electrode (negatrode) materials in lithium-ion batteries (LIBs) due to its high theoretical …

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Electrochemical Synthesis of Multidimensional Nanostructured Silicon as a Negative Electrode Material for Lithium-Ion Battery …

Silicon (Si) is a promising negative electrode material for lithium-ion batteries (LIBs), but the poor cycling stability hinders their practical application. Developing favorable Si nanomaterials is expected to improve their cyclability. Herein, a controllable and facile electrolysis route to prepar …

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The success story of graphite as a lithium-ion anode material – fundamentals, remaining challenges, and recent developments including silicon ...

In a very similar way, the company Nanoscale Components designed a pre-lithiation bath, in which negative electrodes are pre-lithiated from a lithium-salt containing solution, potentially via a roll-to-roll process. 293,294 To demonstrate the general feasibility ofet al.

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In situ-formed nitrogen-doped carbon/silicon-based materials as negative electrodes for lithium-ion batteries …

The development of negative electrode materials with better performance than those currently used in Li-ion technology has been a major focus of recent battery research. Here, we report the synthesis and electrochemical evaluation of in situ-formed nitrogen-doped carbon/SiOC.-formed nitrogen-doped carbon/SiOC.

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Nano-sized Transition Metal Oxide Negative Electrode Materials for Lithium-ion Batteries …

Electrochemical energy storage is introduced in chapter 1, with a focus on high power and high energy negative electrode materials for lithium-ion batteries (and capacitors). Many different classes of materials are discussed with associated advantages and disadvantages.

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Silicon-Carbon composite anodes from industrial battery grade silicon …

batteries stated that there is a lack of research and theory on silicon oxide materials 38. ... M. Electrochemical properties of non-nano-silicon negative electrodes prepared with a polyimide ...

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Nano-sized cobalt oxide/mesoporous carbon sphere composites as negative electrode material for lithium-ion batteries …

Nano-sized cobalt oxide/mesoporous carbon sphere composites as negative electrode material for lithium-ion batteries September 2008 Electrochimica Acta 53(22):6497-6503

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Research progress on carbon materials as negative electrodes in sodium‐ and potassium‐ion batteries …

Due to their abundance, low cost, and stability, carbon materials have been widely studied and evaluated as negative electrode materials for LIBs, SIBs, and PIBs, including graphite, hard carbon (HC), soft carbon (SC), graphene, and so forth. 37-40 Carbon materials have different structures (graphite, HC, SC, and graphene), which can meet the needs for …

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Research progress of nano-silicon-based materials and silicon …

Compared with lead-acid batteries and nickel-hydrogen batteries, LIBs have the advantages of high energy density, good cycling, and good Coulomb efficiency. …

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Silicon-Based Negative Electrode for High-Capacity Lithium-Ion Batteries…

In order to examine whether or not a silicon electrode is intrinsically suitable for the high-capacity negative electrode in lithium-ion batteries, 9–13 a thin film of silicon formed on copper foil is examined in a lithium cell. Figure 1 shows the charge and discharge curves of a 1000 nm thick silicon electrode examined in a lithium cell.

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Advances in Structure and Property Optimizations of Battery Electrode Materials

Different Types and Challenges of Electrode Materials According to the reaction mechanisms of electrode materials, the materials can be divided into three types: insertion-, conversion-, and alloying-type materials (Figure 1 B). 25 The voltages and capacities of representative LIB and SIB electrode materials are summarized in Figures …

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Electrode Degradation in Lithium-Ion Batteries | ACS Nano

Cathodes are the Achilles'' heels of LIBs. With a reversible capacity of 372 mAhg −1, the graphite anode has a capacity much higher than that of the cathode materials that are usually paired with it in commercial batteries small lithium-ion cells, for example, LiCoO 2 (LCO) cathodes with a usable capacity of 160 mAhg −1 and ∼60% lithium …

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Silicon Nanowire Fabric as a Lithium Ion Battery Electrode Material | Journal of the American Chemical Society

A nonwoven fabric with paperlike qualities composed of silicon nanowires is reported. The nanowires, made by the supercritical-fluid–liquid–solid process, are crystalline, range in diameter from 10 to 50 nm with an average length of >100 μm, and are coated with a thin chemisorbed polyphenylsilane shell. About 90% of the nanowire fabric …

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Nano-sized Transition Metal Oxide Negative Electrode …

Electrochemical energy storage is introduced in chapter 1, with a focus on high power and high energy negative electrode materials for lithium-ion batteries (and capacitors).

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Review Article Negative electrode materials for high-energy density Li

Section snippets High-energy Li-ion anodes In the search for high-energy density Li-ion batteries, there are two battery components that must be optimized: cathode and anode. Currently available cathode materials for Li-ion batteries, such as LiNi 1/3 Mn 1/3 Co 1/3 O 2 (NMC) or LiNi 0.8 Co 0.8 Al 0.05 O 2 (NCA) can provide practical specific …

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Research progress on silicon-based materials used as negative …

Silicon-based materials have great potential for application in LIBs anode due to their high energy density, low de-embedded lithium potential, abundant resources, low cost, and …

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Characteristics and electrochemical performances of silicon/carbon nanofiber/graphene composite films as anode materials …

In this study, two-electrode batteries were prepared using Si/CNF/rGO and Si/rGO composite materials as negative electrode active materials for LIBs. To test the electrodes and characterize their electrochemical performances, the prepared Si/CNF/rGO and Si/rGO composite films are cut into small pieces and used as …

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Negative electrode materials for high-energy density Li

The use of high C sp materials, such as silicon, that offers a theoretical specific capacity one order of magnitude higher than graphite, of 4200 mAh g −1 (for Li 22 …

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